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Diaquabis N N diethylnicotinamide kappa N 1 bis 4 fluorobenzoato kappa O copper II       
Yazarlar
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye
Vijdan Öztürk
Kafkas Üniversitesi, Turkey
Vedat Adgüzel
Kafkas Üniversitesi, Turkey
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey
Özet
The asymmetric unit of the title mononuclear Cu II complex, [Cu(C 7H 4FO 2) 2(C 10H 14N 2O) 2(H 2O) 2], contains one-half of the molecule. The Cu II ion is located on an inversion centre, and is coordinated by two N atoms from two diethyl-nicotinamide ligands, two O atoms from two 4-fluoro-benzoate (PFB) ligands and two water molecules in a distorted octa-hedral geometry. In the PFB ligand, the carboxylate group is twisted at an angle of 2.10 (14)° from the attached benzene ring. In the crystal structure, Intermolecular O - H⋯O hydrogen bonds link molecules related by translation along the a axis into chains. Weak Intermolecular C - H⋯O hydrogen bonds and π-π interactions between the pyridine rings of neighbouring molecules [centroid-to-centroid distance = 3.571 (2) Å] further consolidate the crystal packing.
Anahtar Kelimeler
data-to-parameter ratio = 17.6 | mean σ(CC) = 0.002 Å | R factor = 0.033 | single-crystal X-ray study | T = 100 K | wR factor = 0.099
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Dergi ISSN 2056-9890
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 08-2011
Cilt No 67
Sayı 8
Doi Numarası 10.1107/S1600536811029941