| Yazarlar |
Hacali Necefoğlu
|
|
F Elif Özbek
|
|
Vijdan Öztürk
|
|
Barış Tercan
|
|
Tuncer Hökelek
|
| Özet |
| In the crystal structure of the title complex, [Mn(C 7H 4FO 2) 2(H 2O) 2] n , the Mn II atom is located on an inversion centre. It is coordinated by two water mol-ecules in the apical directions and four 4-fluoro-benzoate (PFB) anions, bridging the symmetry related Mn atoms in the basal plane to form an infinite two-dimensional polymeric structure parallel to (100). The four O atoms of the PFB anions around the Mn II atom form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two O atoms of the water mol-ecules. The dihedral angle between the carboxyl-ate group and the adjacent benzene ring is 27.29 (16)°. The O - H⋯O hydrogen bonds further connect the manganese-carboxyl-ate units. π-π contacts between the benzene rings [centroid-centroid distance = 3.6894 (15) Å] further stabilize the crystal structure. © Necefoǧlu et al. 2011. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E |
| Dergi ISSN | 1600-5368 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2011 |
| Cilt No | 67 |
| Sayfalar | 1003 / |
