Diaquabis N N diethylnicotinamide kappa N 1 bis 4 ethylbenzoato kappa O copper II
Yazarlar (5)
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Ali Marac
Kafkas Üniversitesi, Türkiye
Kafkas Üniversitesi, Türkiye
Vedat Akta
Kafkas Üniversitesi, Türkiye
Kafkas Üniversitesi, Türkiye
Bar Tercan
Karabük Üniversitesi, Türkiye
Karabük Üniversitesi, Türkiye
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hacettepe Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 06-2011 |
| Cilt / Sayı / Sayfa | 67 / 6 / – | DOI | 10.1107/S1600536811018666 |
| Özet |
| The title CuII complex, [Cu(C9H9O 2)2(C10H14N2O) 2(H2O)2], contains two 4-ethyl-benzoate (PEB) ligands, two monodentate diethyl-nicotinamide (DENA) ligands and two water mol-ecules. The four O atoms in the equatorial plane around the CuII ion form a slightly distorted square-planar arrangement, while the distorted octa-hedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. Intra-molecular O - H⋯O hydrogen bonds link the water mol-ecules to the carboxyl-ate groups. The dihedral angles between the carboxyl-ate groups and the adjacent benzene rings are 4.6 (3) and 3.7 (2)°, while the pyridine rings and the benzene rings are oriented at dihedral angles of 6.82 (11) and 3.63 (14)°. In the crystal, inter-molecular O - H⋯O hydrogen bonds link the mol-ecules into chains propagating along [010]. C - H⋯O inter-actions and a π-π contact between the pyridine rings [centroid-centroid distance = 3.469 (2) Å] are also observed. |
| Anahtar Kelimeler |