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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 11-2009 |
| Cilt / Sayı / Sayfa | 65 / 11 / – | DOI | 10.1107/S1600536809042640 |
| Makale Linki | https://journals.iucr.org/e/issues/2009/11/00/xu2635/xu2635.pdf | ||
| Özet |
| The asymmetric unit of the title CdII complex, [Cd(C8H5O3)2(C6H6N2O)2(H2O)]·H2O, contains two 4-formylbenzoate (FB), two isonicotinamide (INA) ligands, one coordinated and one uncoordinated water molecule; the FB ions act as bidentate ligands. The coordination number of the Cd(II) atom is seven within a CdO5N2 donor set. Intramolecular O—H⋯O hydrogen bonds link the uncoordinated water molecules to the carboxyl groups. The dihedral angle between the carboxylate groups and the adjacent benzene rings are 17.53 (13) and 16.55 (14)°. In the crystal structure, intermolecular O—H⋯O, N—H⋯O, N—H⋯N and C—H⋯O hydrogen bonds link the molecules into a supramolecular structure. The amide group of one of the INA ligands is disordered over two orientations, with an occupancy ratio of 0.759 (3):0.241 (3). |
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| Google Scholar | 32 |
| Web of Science | 21 |
| Scopus | 2 |