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Bis isonicotinamide kappa N 1 bis 4 methylamino benzoato zinc II monohydrate        
Yazarlar
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey
Hakan Dal
Anadolu Üniversitesi, Turkey
Bariş Tercan
Karabük Üniversitesi, Turkey
Özgür Aybirdi
Kafkas Üniversitesi, Turkey
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Özet
In the title ZnII complex, [Zn(C8H8NO 2)2(C6H6N2O) 2]·H2O, the Zn atom is coordinated by two 4-methyl-amino-benzoate (MAB) and two isonicotinamide (INA) ligands in a distorted trigonal-bipyramidal geometry; one of the MAB ions acts as a bidentate ligand while the other MAB and the two INA are monodentate ligands. The dihedral angles between the carboxyl groups and the adjacent benzene rings are 8.52 (22) and 5.10 (14)°. In the crystal, inter-molecular O- H⋯O and N- H⋯O hydrogen bonding links the mol-ecules into a supra-molecular structure. Weak inter-molecular C- H⋯O inter-actions are also present.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Dergi ISSN 2056-9890
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 11-2009
Cilt No 65
Sayı 11
Doi Numarası 10.1107/S1600536809041208