Bis mu 2 fluorobenzoato 1 2 kappa 2 O O 2 fluorobenzoato 1 kappa 2 O O 2 fluorobenzoato 2 kappa O dinicotinamide 1 kappa N 1 2 kappa N 1 dizinc II 2 fluorobenzoic acid 1 1
Yazarlar (5)
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2009 |
| Cilt No | 65 |
| Sayfalar | 1608 / |
| Özet |
| The asymmetric unit of the title compound, [Zn-2(C7H4FO2)(4)(C6H6N2O)(2)]center dot C7H5FO2, consists of a binuclear Zn-II complex bridged by two carboxyl groups of 2-fluorobenzoate (FB) anions and a 2-fluorobenzoic acid molecule. The two bridging FB anions, one chelating FB anion and one nicotinamide (NA) ligand coordinate to one Zn cation with a distorted square-pyramidal geometry, while the two bridging FB anions, one monodentate FB anion and one NA ligand coordinate to the other Zn cation with a distorted tetrahedral geometry. Within the binuclear molecule, the pyridine rings are oriented at a dihedral angle of 19.41 (14)degrees. In the crystal structure, the uncoordinated 2-fluorobenzoic acid molecules are linked by O-H center dot center dot center dot O hydrogen bonding, forming centrosymmetric supramolecular dimers. Intermolecular N-H center dot center dot center dot O hydrogen bonds … |
| Anahtar Kelimeler |
