Tetraaquabis isonicotinamide kappa N 1 nickel II bis 4 formylbenzoate dihydrate
Yazarlar (5)
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Filiz Ylmaz
Anadolu Üniversitesi, Türkiye
Bar Tercan
Karabük Üniversitesi, Türkiye
Ferdi Gürgen
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
| Makale Türü |
Özgün Makale
(SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
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| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 09-2009 |
| Cilt / Sayı / Sayfa | 65 / 9 / – | DOI | 10.1107/S1600536809032279 |
| Özet |
| The asymmetric unit of the title complex, [Ni(C6H 6N2O)2(H2O)4](C 8H5O3)2·2H2O, contains one-half of the complex cation with the NiII atom located on an inversion center, a 4-formyl-benzoate (FB) counter-anion and an uncoordinated water mol-ecule. The four O atoms in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement and the slightly distorted octa-hedral coordination is completed by the two N atoms of the isonicotinamide (INA) ligands at a sligthly longer distance in the axial positions. The dihedral angle between the carboxyl-ate group and the attached benzene ring is 8.14 (11)°, while the pyridine and benzene rings are oriented at a dihedral angle of 3.46 (6)°. In the crystal structure, O - H⋯O, N - H⋯O and C - H⋯O hydrogen bonds link the molecules into a three-dimensional network. π-π Contacts between the benzene and pyridine rings [centroid-centroid distance = 3.751 (1) Å] may further stabilize the crystal structure. © Ḧkelek et al. 2009. |
| Anahtar Kelimeler |
Science Direct
Tetraaquabis isonicotinamide kappa N 1 nickel II bis 4 formylbenzoate dihydrate
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| WoS | 6 |
| SCOPUS | 8 |
| Google Scholar | 17 |
| ResearchGate | 11 |