| Yazarlar |
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey |
|
Hakan Dal
Anadolu Üniversitesi, Turkey |
|
Bar Tercan
Karabük Üniversitesi, Turkey |
|
Özgür Aybirdi
Kafkas Üniversitesi, Turkey |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
| Özet |
| The title CoII complex, [Co(C9H10NO 2)2(C10H14N2O) 2(H2O)2], is centrosymmetric. It contains two dimethyl-amino-benzoate (DMAB) and two diethyl-nicotinamide (DENA) ligands and two water molecules, all of them being monodentate. The four O atoms in the equatorial plane around the Co atom form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two pyridine N atoms of DENA ligands with the Co - N distance of 2.1519 (11) Å in the axial positions. The Co atom is displaced out of the least-squares plane of the carboxyl-ate group by -0.781 (1) Å. The dihedral angle between the carboxyl-ate group and the adjacent benzene ring is 5.05 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 71.48 (5)°. In the crystal structure, inter-molecular O - H⋯O and C - H⋯O hydrogen bonds link the molecules into a three-dimensional network. Two weak C - H⋯π inter-actions are also present. © Hökelek et al. 2009. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE |
| Dergi ISSN | 2056-9890 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Makale Dili | İngilizce |
| Basım Tarihi | 09-2009 |
| Cilt No | 65 |
| Sayı | 9 |
| Doi Numarası | 10.1107/S1600536809030980 |
