Diaquabis N N diethylnicotinamide kappa N 1 bis 4 dimethylamino benzoato kappa O cobalt II
Yazarlar (5)
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Prof. Dr. Hakan Dal Anadolu Üniversitesi, Türkiye
Bar Tercan
Karabük Üniversitesi, Türkiye
Özgür Aybirdi
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section E Structure Reports Online
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2009
Kabul Tarihi 04-08-2009 Yayınlanma Tarihi 08-08-2009
Cilt / Sayı / Sayfa 65 / 9 / – DOI 10.1107/S1600536809030980
Makale Linki https://journals.iucr.org/e/issues/2009/09/00/xu2578/xu2578.pdf
UAK Araştırma Alanları
Anorganik Kimya
Özet
The title CoII complex, [Co(C9H10NO2)2(C10H14N2O)2(H2O)2], is centrosymmetric. It contains two dimethylaminobenzoate (DMAB) and two diethylnicotinamide (DENA) ligands and two water molecules, all of them being monodentate. The four O atoms in the equatorial plane around the Co atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of DENA ligands with the Co—N distance of 2.1519 (11) Å in the axial positions. The Co atom is displaced out of the least-squares plane of the carboxylate group by −0.781 (1) Å. The dihedral angle between the carboxylate group and the adjacent benzene ring is 5.05 (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 71.48 (5)°. In the crystal structure, intermolecular O—H⋯O and C—H⋯O hydrogen bonds link the molecules into a three …
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