Tetrakis mu 4 diethylamino benzoato kappa 2 O O bis N N diethylnicotinamide kappa N 1 zinc II
Yazarlar (5)
Hökelek Tuncer
Yılmaz Filiz
Tercan Barış
Aybirdi Özgür
Necefoğlu Hacali
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2009 |
| Cilt / Sayı / Sayfa | 65 / 8 / 955– | DOI | – |
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| In the centrosymmetric binuclear title complex, [Zn2(C11H14NO2)4(C10H14N2O)2], the two ZnII ions [Zn⋯Zn = 2.8874 (3) Å] are bridged by four 4-(diethylamino)benzoate (DEAB) ligands. The four nearest O atoms around each ZnII ion form a distorted square-planar arrangement, the distorted square-pyramidal coordination being completed by the pyridine N atom of an N,N-diethylnicotinamide (DENA) ligand at a distance of 2.0484 (12) Å. The dihedral angle between the benzene ring and the carboxylate group is 4.89 (6)° in one of the independent DEAB ligands and 7.13 (7)° in the other. The benzene rings of the two independent DEAB ligands are oriented at a dihedral angle of 86.58 (5)°. The pyridine ring is oriented at dihedral angles of 31.17 (4) and 58.38 (4)° with respect to the two benzene rings. In the crystal, weak intermolecular C—H⋯O interactions link the molecules into a three-dimensional … |
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