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Diaquabis 4 dimethylamino benzoato kappa O bis nicotinamide kappa N 1 zinc II dihydrate        
Yazarlar
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey
Ertuǧrul Gazi Saǧlam
Ankara Üniversitesi, Turkey
Bariş Tercan
Karabük Üniversitesi, Turkey
Özgür Aybirdi
Kafkas Üniversitesi, Turkey
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Özet
In the centrosymmetric title structure, [Zn(C9H 10NO2)2(C6H6N 2O)2(H2O)2]·2H2O, the ZnII cation, located on an inversion center, is coordinated by two 4-(methyl-amino)-benzoate anions, two nicotinamide ligands and two water molecules in a slightly distorted octa-hedral geometry. The dihedral angle between the carboxyl-ate group and the attached benzene ring is 3.09 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 77.10 (4)°. The uncoordinated water molecule is linked to nicotinamide ligands by O - H⋯O hydrogen bonds. In the crystal, inter-molecular N - H⋯O, O - H⋯O and C - H⋯O hydrogen bonds link the molecules into a three-dimensional network. A weak N - H⋯π inter-action also occurs.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Dergi ISSN 2056-9890
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 12-2010
Cilt No 66
Sayı 12
Doi Numarası 10.1107/S1600536810046854