Yazarlar |
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey |
Ertuǧrul Gazi Saǧlam
Ankara Üniversitesi, Turkey |
Bariş Tercan
Karabük Üniversitesi, Turkey |
Özgür Aybirdi
Kafkas Üniversitesi, Turkey |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
Özet |
In the centrosymmetric title structure, [Zn(C9H 10NO2)2(C6H6N 2O)2(H2O)2]·2H2O, the ZnII cation, located on an inversion center, is coordinated by two 4-(methyl-amino)-benzoate anions, two nicotinamide ligands and two water molecules in a slightly distorted octa-hedral geometry. The dihedral angle between the carboxyl-ate group and the attached benzene ring is 3.09 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 77.10 (4)°. The uncoordinated water molecule is linked to nicotinamide ligands by O - H⋯O hydrogen bonds. In the crystal, inter-molecular N - H⋯O, O - H⋯O and C - H⋯O hydrogen bonds link the molecules into a three-dimensional network. A weak N - H⋯π inter-action also occurs. |
Anahtar Kelimeler |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
Dergi ISSN | 2056-9890 |
Dergi Tarandığı Indeksler | SCI-Expanded |
Makale Dili | İngilizce |
Basım Tarihi | 12-2010 |
Cilt No | 66 |
Sayı | 12 |
Doi Numarası | 10.1107/S1600536810046854 |