catena Poly 4 methylbenzoato kappa O manganese II mu aqua bis mu 4 methylbenzoato kappa 2 O O 4 methylbenzoato kappa O manganese II bis mu N N diethylnicotinamide kappa 2 N 3 O O N 3
Yazarlar (5)
Hökelek Tuncer
Dal Hakan
Tercan Barış
Çimen Efdal
Necefoğlu Hacali
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2010 |
| Cilt / Sayı / Sayfa | 66 / 7 / 734– | DOI | – |
| UAK Araştırma Alanları |
Anorganik Kimya
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| Özet |
| The asymmetric unit of the title complex, [Mn2(C8H7O2)4(C10H14N2O)2(H2O)]n, contains two crystallographically independent units. In each one, the MnII ions are bridged by two 4-methylbenzoate (PMB) ligands and one water molecule. In the crystal structure, each MnII ion is coordinated by three PMB ligands, one water molecule and two symmetry-related N,N-diethylnicotinamide (DENA) ligands. Symmetry-related MnII ions are bridged by the N and O atoms of symmetry-related DENA ligands, forming polymeric chains parallel to [100]. The coordination environmnts for the MnII ions are slightly distorted octahedral. Intramolecular O—H⋯O hydrogen bonds link bridging water molecules to the carboxylate O atoms of a neighboring polymeric chain. In the crystal structure, π–π contacts between benzene rings [centroid–centroid distance = 3.562 (1) Å] and weak C—H⋯π interactions are also observed. |
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