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Diaquabis 2 bromobenzoato kappa O bis N N diethylnicotinamide kappa N 1 cobalt II       
Yazarlar
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey
Güner Saka
Hitit University, Turkey
Bar Tercan
Karabük Üniversitesi, Turkey
 Füreya Elif ÖZTÜRKKAN Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye
 Hacali NECEFOĞLU Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Özet
In the mononuclear title compound, [Co(C7H4BrO 2)2(C10H14N2O) 2(H2O)2], the CoII ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 2-bromobenzoate anion, one diethylnicotinamide (DENA) ligand and one coordinated water molecule; all ligands are monodentate. The four O atoms in the equatorial plane around CoII form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the DENA ligands in axial positions. The dihedral angle between the carboxylate group and the attached benzene ring is 84.7 (1)°; the pyridine and benzene rings are oriented at a dihedral angle of 43.64 (6)°. In the crystal structure, intermolecular O-H⋯O and C-H⋯O hydrogen bonds link the molecules into a three-dimensional network.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Dergi ISSN 2056-9890
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 09-2010
Cilt No 66
Sayı 9
Doi Numarası 10.1107/S1600536810032630