Diaquabis 2 bromobenzoato kappa O bis N N diethylnicotinamide kappa N 1 cobalt II
Yazarlar (5)
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Öğr. Gör. Güner Saka Hitit University, Türkiye
Bar Tercan
Karabük Üniversitesi, Türkiye
Doç. Dr. Füreya Elif ÖZTÜRKKAN Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section E Structure Reports Online
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2010
Kabul Tarihi 13-08-2010 Yayınlanma Tarihi 18-08-2010
Cilt / Sayı / Sayfa 66 / 9 / – DOI 10.1107/S1600536810032630
Makale Linki https://journals.iucr.org/e/issues/2010/09/00/im2218/im2218.pdf
UAK Araştırma Alanları
Anorganik Kimya
Özet
In the mononuclear title compound, [Co(C7H4BrO2)2(C10H14N2O)2(H2O)2], the CoII ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 2-bromobenzoate anion, one diethylnicotinamide (DENA) ligand and one coordinated water molecule; all ligands are monodentate. The four O atoms in the equatorial plane around CoII form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the DENA ligands in axial positions. The dihedral angle between the carboxylate group and the attached benzene ring is 84.7 (1)°; the pyridine and benzene rings are oriented at a dihedral angle of 43.64 (6)°. In the crystal structure, intermolecular O—H⋯O and C—H⋯O hydrogen bonds link the molecules into a three-dimensional network.
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