| Yazarlar |
Tuncer Hökelek
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Güner Saka
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Barış Tercan
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F Elif Öztürkkan
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Hacali Necefoğlu
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| Özet |
| In the mononuclear title compound, [Co(C7H4BrO 2)2(C10H14N2O) 2(H2O)2], the CoII ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 2-bromobenzoate anion, one diethylnicotinamide (DENA) ligand and one coordinated water molecule; all ligands are monodentate. The four O atoms in the equatorial plane around CoII form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two pyridine N atoms of the DENA ligands in axial positions. The dihedral angle between the carboxylate group and the attached benzene ring is 84.7 (1)°; the pyridine and benzene rings are oriented at a dihedral angle of 43.64 (6)°. In the crystal structure, intermolecular O-H⋯O and C-H⋯O hydrogen bonds link the molecules into a three-dimensional network. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E |
| Dergi ISSN | 1600-5368 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2010 |
| Cilt No | 66 |
| Sayfalar | 1132 / |
