Bis mu 4 methylamino benzoato kappa 3 O O O kappa 3 O O O bis aqua 4 methylamino benzoato kappa 2 O O nicotinamide kappa N cadmium II
Yazarlar (5)
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2010 |
| Cilt / Sayı / Sayfa | 66 / 0 / 1559– | DOI | – |
| Özet |
| In the dinuclear centrosymmetric Cd-II compound, [Cd-2(C8H8NO2)(4)(C6H6N2O)(2)(H2O)(2)], the metal atom is chelated by two carboxylate groups from 4-(methylamino)benzoate (PMAB) anions, and coordinated by one nicotinamide and one water molecule; a carboxylate O atom from the adjacent PMAB anion bridges to the Cd atom, completing the irregular seven-coordination geometry. In the crystal, intermolecular O-H center dot center dot center dot O, N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds link the molecules into a three-dimensional network. pi-pi contacts between the pyridine rings [centroid-centroid distance = 3.965 (1) angstrom] may further stabilize the structure. A weak C-H center dot center dot center dot pi interaction also occurs. |
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