Yazarlar |
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey |
Güner Saka
Hitit University, Turkey |
Bariş Tercan
Karabük Üniversitesi, Turkey |
Efdal Çimen
Kafkas Üniversitesi, Turkey |
Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
Özet |
In the centrosymmetric title compound, [Cu(C8H7O 2)2(C6H6N2O) 2]·2H2O, the CuII ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 4-methylbenzoate anion, one isonicotinamide (INA) ligand and one uncoordinated water molecule; all the ligands are monodentate. The two O and the two N atoms around the CuII ion form a slightly distorted square-planar arrangement. The dihedral angle between the carboxyl-ate group and the attached benzene ring is 13.86 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 86.08 (5)°. The uncoordinated water molecules are linked to the INA ligands by O - H⋯O hydrogen bonds. In the crystal structure, intermolecular O - H⋯O, N - H⋯O and C - H⋯O hydrogen bonds link the molecules into a three-dimensional network. |
Anahtar Kelimeler |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E |
Dergi ISSN | 1600-5368 |
Dergi Tarandığı Indeksler | SCI-Expanded |
Makale Dili | İngilizce |
Basım Tarihi | 01-2010 |
Cilt No | 66 |
Sayı | 8 |
Sayfalar | 955 / 0 |
Doi Numarası | 10.1107/S1600536810028060 |
Atıf Sayıları | |
SCOPUS | 2 |
ResearchGate | 3 |