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Bis isonicotinamide kN1 bis 4 methylbenzoato kO copper II dihydrate    
Yazarlar
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey
Güner Saka
Hitit University, Turkey
Bariş Tercan
Karabük Üniversitesi, Turkey
Efdal Çimen
Kafkas Üniversitesi, Turkey
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Özet
In the centrosymmetric title compound, [Cu(C8H7O 2)2(C6H6N2O) 2]·2H2O, the CuII ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 4-methylbenzoate anion, one isonicotinamide (INA) ligand and one uncoordinated water molecule; all the ligands are monodentate. The two O and the two N atoms around the CuII ion form a slightly distorted square-planar arrangement. The dihedral angle between the carboxyl-ate group and the attached benzene ring is 13.86 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 86.08 (5)°. The uncoordinated water molecules are linked to the INA ligands by O - H⋯O hydrogen bonds. In the crystal structure, intermolecular O - H⋯O, N - H⋯O and C - H⋯O hydrogen bonds link the molecules into a three-dimensional network.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 01-2010
Cilt No 66
Sayı 8
Sayfalar 955 / 0
Doi Numarası 10.1107/S1600536810028060
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
SCOPUS 2
ResearchGate 3
Bis isonicotinamide kN1 bis 4 methylbenzoato kO copper II dihydrate

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