Bis isonicotinamide kN1 bis 4 methylbenzoato kO copper II dihydrate
   
Yazarlar (5)
Tuncer Hökelek Hacettepe Üniversitesi, Türkiye
Güner Saka Hitit University, Türkiye
Bariş Tercan Karabük Üniversitesi, Türkiye
Dr. Öğr. Üyesi Efdal ÇİMEN Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section E Structure Reports Online
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2010
Cilt / Sayı / Sayfa 66 / 8 / – DOI 10.1107/S1600536810028060
Özet
In the centrosymmetric title compound, [Cu(C8H7O 2)2(C6H6N2O) 2]·2H2O, the CuII ion is located on a crystallographic inversion center. The asymmetric unit is completed by one 4-methylbenzoate anion, one isonicotinamide (INA) ligand and one uncoordinated water molecule; all the ligands are monodentate. The two O and the two N atoms around the CuII ion form a slightly distorted square-planar arrangement. The dihedral angle between the carboxyl-ate group and the attached benzene ring is 13.86 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 86.08 (5)°. The uncoordinated water molecules are linked to the INA ligands by O - H⋯O hydrogen bonds. In the crystal structure, intermolecular O - H⋯O, N - H⋯O and C - H⋯O hydrogen bonds link the molecules into a three-dimensional network.
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