| Yazarlar |
Tuncer Hökelek
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Hakan Dal
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Barış Tercan
|
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Efdal Çimen
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Hacali Necefoğlu
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| Özet |
| In the title compound, [Pb(C8H7O2) 2(C6H6N2O)]n , the PbII ion is coordinated by two 4-methylbenzoate (PMB) and one nicotinamide (NA) ligands while symmetry-related NA ligands bridge adjacent PbII ions, forming polymeric chains along the c axis. The carboxyl-ate groups in the two PMB ions are twisted away from the attached benzene ring by 22.9 (2) and 4.6 (2)°. The two benzene rings of the PMB ions are oriented at a dihedral angle of 83.7 (1)°. In a polymeric chain, the NA ligands are linked to PMB ions through intramolecular N - H⋯O hydrogen bonds. In the crystal structure, adjacent polymeric chains interact via N - H⋯O and C - H⋯O hydrogen bonds, forming a two-dimensional network parallel to the bc plane. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E |
| Dergi ISSN | 1600-5368 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2010 |
| Cilt No | 66 |
| Sayfalar | 953 / |
