Yazarlar |
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey |
Hakan Dal
Anadolu Üniversitesi, Turkey |
Bariş Tercan
Karabük Üniversitesi, Turkey |
Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye |
Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
Özet |
In the monomeric and centrosymmetric title NiII complex, [Ni(C7H4ClO2)2(C10H14N2O)2(H2O)2], the NiII ion is located on an inversion center. The asymmetric unit contains one 2-chloro-benzoate ligand, one diethyl-nicotinamide (DENA) ligand and one coordinating water mol-ecule, the ligands being monodentate. The four O atoms in the equatorial plane around the NiII ion form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by two N atoms of the DENA ligands in axial positions. The dihedral angle between the benzene ring and the attached carboxyl-ate group is 87.36 (10)°, while the pyridine and benzene rings are oriented at an angle of 41.90 (5)°. In the crystal structure, inter-molecular O - H⋯O hydrogen bonds link the mol-ecules into a two-dimensional network parallel to (10 ). |
Anahtar Kelimeler |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
Dergi ISSN | 2056-9890 |
Dergi Tarandığı Indeksler | SCI-Expanded |
Makale Dili | İngilizce |
Basım Tarihi | 05-2009 |
Cilt No | 65 |
Sayı | 65 |
Doi Numarası | 10.1107/S1600536809014226 |
Atıf Sayıları | |
WoS | 9 |
SCOPUS | 9 |