Tetrakis benzoato bis N N diethylnicotinamide dicopper II
Yazarlar (3)
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | ||
| Dergi ISSN | 0108-2701 | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 10-1995 |
| Cilt / Sayı / Sayfa | 51 / 51 / 2020–2023 | DOI | 10.1107/S0108270195000618 |
| Özet |
| Abstract The title molecule,[Cu2 (C6HsCOO) 4 (CIoH14N20) 2], is a crystallographically centrosymmetric binuclear com-plex, with Cu atoms [Cu-.-Cu'= 2.613 (1) A.] bridged by four benzoate ligands. The four nearest O atoms around each Cu atom form a square-planar arrange-ment with the square-pyramidal coordination completed by the pyridine N atom of the N, N£ diethylnicotinamide ligand at a distance of 2.162 (6) A. Each Cu atom is displaced by 0.190 (1)~, from the plane of the four O atoms, with an average Cu--O distance of 1.974 (6)~.Comment N, N-Diethylnicotinamide (DENA) is known as an important respiration stimulant. The structures of some complexes obtained from the reactions of transi-tion metal (II) ions with DENA have been deter-mined previously: Cd (DENA)(SCN) 2 (Bigoli, Braibanti, Pellinghelli & Tiripicchio, 1972), Mn (DENA) 2 (NCS) 2 (Bigoli, Braibanti, Pellinghelli & Tiripicchio, 1973a), Zn … |
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| Google Scholar | 62 |
| Web of Science | 55 |