Yazarlar |
Mustafa SERTÇELİK
Kafkas Üniversitesi, Türkiye |
Bar Tercan
Karabük Üniversitesi, Turkey |
Ertan Ahin
Atatürk Üniversitesi, Turkey |
Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey |
Özet |
In the title centrosymmetric mononuclear NiII compound, [Ni(C8H5O3)2(C10H 14N2O)2(H2O)2], the central NiII atom is coordinated by two O atoms from two 4-formyl-benzoate (FOB) ligands, two O atoms from two water mol-ecules and two N atoms from two diethyl-nicotinamide (DENA) ligands. The coordination geometry is slightly distorted octa-hedral, with four O atoms in the equatorial plane and two N atoms in axial positions. Intra-molecular O - H⋯O hydrogen bonds are observed. In the crystal structure, mol-ecules are linked into chains along the a axis by inter-molecular O - H⋯O hydrogen bonds. The structure is further stabilized by π-π inter-actions between the pyridine rings of DENA units, with a centroid-centroid distance of 3.668 (2) Å. |
Anahtar Kelimeler |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
Dergi ISSN | 2056-9890 |
Dergi Tarandığı Indeksler | SCI-Expanded |
Makale Dili | İngilizce |
Basım Tarihi | 03-2009 |
Cilt No | 65 |
Sayı | 3 |
Doi Numarası | 10.1107/S1600536809006345 |
Atıf Sayıları | |
WoS | 14 |
SCOPUS | 14 |