| Yazarlar (5) |
|
Hacettepe Üniversitesi, Türkiye |
|
Anadolu Üniversitesi, Türkiye |
|
Karabük Üniversitesi, Türkiye |
Doç. Dr. Füreya Elif ÖZTÜRKKAN
Kafkas Üniversitesi, Türkiye |
Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye |
| Özet |
| In the monomeric centrosymmetric title NiII complex, [Ni(C 7H4BrO2)2(C10H 14N2O)2(H2O)2], the NiII ion is located on an inversion center. The asymmetric unit contains one 2-bromo-benzoate ligand, one diethyl-nicotinamide (DENA) ligand and one coordinated water mol-ecule. The four O atoms in the equatorial plane around the NiII ion form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by two N atoms of two DENA ligands in the axial positions. The dihedral angle between the benzene ring and the attached carboxyl-ate group is 87.73 (15)°, while the pyridine and benzene rings are oriented at a dihedral angle of 42.48 (7)°. In the crystal structure, O - H⋯O hydrogen bonds link the mol-ecules into a two-dimensional network parallel to (10 ). In addition, C - H⋯O hydrogen bonds are observed. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS |
| Dergi ISSN | 2056-9890 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Makale Dili | İngilizce |
| Basım Tarihi | 07-2009 |
| Cilt No | 65 |
| Sayı | 65 |
| Doi Numarası | 10.1107/S1600536809021795 |
| Atıf Sayıları | |
| WoS | 4 |
| SCOPUS | 2 |