catena Poly diaquabis 4 diethylamino benzoato kappa O manganese II mu aqua dihydrate
       
Yazarlar (5)
Tuncer Hökelek
Hacettepe Üniversitesi, Türkiye
Hakan Dal Anadolu Üniversitesi, Türkiye
Bar Tercan
Karabük Üniversitesi, Türkiye
Özgür Aybirdi
Kafkas Üniversitesi, Türkiye
Prof. Dr. Hacali NECEFOĞLU Kafkas Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Acta Crystallographica Section E Structure Reports Online
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 07-2009
Cilt / Sayı / Sayfa 65 / 7 / – DOI 10.1107/S1600536809021060
Makale Linki https://doi.org/10.1107/s1600536809021060
Özet
In the crystal structure of the title complex, {[Mn(C11H 14NO2)2(H2O)3] ·2H2O}n , the two independent MnII atoms are located on a centre of symmetry and coordinated by two 4-(diethyl-amino) benzoate (DEAB) anions and two water mol-ecules in the basal plane while another water mol-ecule bridges the Mn atoms in the apical directions, forming polymeric chains. The dihedral angles between the carboxyl-ate groups and the adjacent benzene rings are 11.33 (13) and 10.90 (9)° and the benzene rings are oriented at a dihedral angle of 67.88 (6)°. The uncoordinated water mol-ecules link the carboxyl-ate groups and coordinated water mol-ecules via O - H⋯O hydrogen bonding. Weak C - H⋯π inter-actions are also found in the crystal structure.
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