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catena Poly diaquabis 4 diethylamino benzoato kappa O manganese II mu aqua dihydrate      
Yazarlar
Tuncer Hökelek
Hakan Dal
Barış Tercan
Özgür AybirdiHacali Necefoğlu
Özet
In the crystal structure of the title complex, {[Mn(C11H 14NO2)2(H2O)3] ·2H2O}n , the two independent MnII atoms are located on a centre of symmetry and coordinated by two 4-(diethyl-amino) benzoate (DEAB) anions and two water mol-ecules in the basal plane while another water mol-ecule bridges the Mn atoms in the apical directions, forming polymeric chains. The dihedral angles between the carboxyl-ate groups and the adjacent benzene rings are 11.33 (13) and 10.90 (9)° and the benzene rings are oriented at a dihedral angle of 67.88 (6)°. The uncoordinated water mol-ecules link the carboxyl-ate groups and coordinated water mol-ecules via O - H⋯O hydrogen bonding. Weak C - H⋯π inter-actions are also found in the crystal structure.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E
Dergi ISSN 1600-5368
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 01-2009
Sayı 65
Sayfalar 747 /
Atıf Sayıları
WoS 3
SCOPUS 3
ResearchGate 3

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