Yazarlar |
Tuncer Hökelek
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Hakan Dal
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Barış Tercan
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Özgür AybirdiHacali Necefoğlu
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Özet |
In the crystal structure of the title complex, {[Mn(C11H 14NO2)2(H2O)3] ·2H2O}n , the two independent MnII atoms are located on a centre of symmetry and coordinated by two 4-(diethyl-amino) benzoate (DEAB) anions and two water mol-ecules in the basal plane while another water mol-ecule bridges the Mn atoms in the apical directions, forming polymeric chains. The dihedral angles between the carboxyl-ate groups and the adjacent benzene rings are 11.33 (13) and 10.90 (9)° and the benzene rings are oriented at a dihedral angle of 67.88 (6)°. The uncoordinated water mol-ecules link the carboxyl-ate groups and coordinated water mol-ecules via O - H⋯O hydrogen bonding. Weak C - H⋯π inter-actions are also found in the crystal structure. |
Anahtar Kelimeler |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | ACTA CRYSTALLOGRAPHICA SECTION E |
Dergi ISSN | 1600-5368 |
Dergi Tarandığı Indeksler | SCI-Expanded |
Makale Dili | İngilizce |
Basım Tarihi | 01-2009 |
Sayı | 65 |
Sayfalar | 747 / |