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catena Poly diaquabis 4 diethylamino benzoato kappa O manganese II mu aqua dihydrate       
Yazarlar
Tuncer Hökelek
Hacettepe Üniversitesi, Turkey
Hakan Dal
Anadolu Üniversitesi, Turkey
Bar Tercan
Karabük Üniversitesi, Turkey
Özgür Aybirdi
Kafkas Üniversitesi, Turkey
Prof. Dr. Hacali NECEFOĞLU Prof. Dr. Hacali NECEFOĞLU
Kafkas Üniversitesi, Türkiye
Özet
In the crystal structure of the title complex, {[Mn(C11H 14NO2)2(H2O)3] ·2H2O}n , the two independent MnII atoms are located on a centre of symmetry and coordinated by two 4-(diethyl-amino) benzoate (DEAB) anions and two water mol-ecules in the basal plane while another water mol-ecule bridges the Mn atoms in the apical directions, forming polymeric chains. The dihedral angles between the carboxyl-ate groups and the adjacent benzene rings are 11.33 (13) and 10.90 (9)° and the benzene rings are oriented at a dihedral angle of 67.88 (6)°. The uncoordinated water mol-ecules link the carboxyl-ate groups and coordinated water mol-ecules via O - H⋯O hydrogen bonding. Weak C - H⋯π inter-actions are also found in the crystal structure.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Dergi ISSN 2056-9890
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 07-2009
Cilt No 65
Sayı 65
Doi Numarası 10.1107/S1600536809021060