| Makale Türü |
|
||
| Dergi Adı | Acta Crystallographica Section E Structure Reports Online | ||
| Dergi ISSN | 1600-5368 | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 07-2009 |
| Cilt / Sayı / Sayfa | 65 / 7 / – | DOI | 10.1107/S1600536809021060 |
| Makale Linki | https://doi.org/10.1107/s1600536809021060 | ||
| Özet |
| In the crystal structure of the title complex, {[Mn(C11H 14NO2)2(H2O)3] ·2H2O}n , the two independent MnII atoms are located on a centre of symmetry and coordinated by two 4-(diethyl-amino) benzoate (DEAB) anions and two water mol-ecules in the basal plane while another water mol-ecule bridges the Mn atoms in the apical directions, forming polymeric chains. The dihedral angles between the carboxyl-ate groups and the adjacent benzene rings are 11.33 (13) and 10.90 (9)° and the benzene rings are oriented at a dihedral angle of 67.88 (6)°. The uncoordinated water mol-ecules link the carboxyl-ate groups and coordinated water mol-ecules via O - H⋯O hydrogen bonding. Weak C - H⋯π inter-actions are also found in the crystal structure. |
| Anahtar Kelimeler |